- Tom Burke - Fedor Dolokhov
- Tuppence Middleton - Helene Kuragin
- Adrian Edmondson - Ilya Rostov
- Brian Cox - Mikhail Kutuzov
- Jack Lowden - Nikolai Rostov
- Stephen Rea - Vassily Kuragin
- Ken Stott - Bazdeev
- Rebecca Front - Anna Mikhailovna
- Jim Broadbent - Prince Bolkonsky
- Kenneth Cranham - Uncle Mikhail
- Callum Turner - Anatole Kuragin
- Mathieu Kassovitz - Napoleon Bonaparte
- Pip Torrens - Prince Bagration
- Chloe Pirrie - Julie Karegina
- Laurent Maurel - French Viscount
- Kate Phillips - Lise Bolkonskaya
- Kit Connor - Petya Rostov
- Vesta Grabštaitė - Rostov Maid
- Fenella Woolgar - Catiche Kuragina
- Ferdinandas Jakšys - Old Count Bezukhov
- Julia Rayner - Sophie Bezukhova
- David Quilter - Tikhon
- Jolyon Coy - Kaisorov
- Ludger Pistor - General Mack
- Thomas Arnold - Vassily Denisov
- Oscar Pearce - Lieutenant Colonel
- Petras Kuneika - Pierre's Friend
- Michael Epp - Austrian Official
- William Brand - Austrian War Minister
- Benjamin Wainwright - Captain Berg
- Ben Lloyd-Hughes - Tsar Alexander
- Guillaume Faure - Napoleon's Adjutant
- Vilius Tumalavicius - Retreating Soldier 1
- Vygandas Vadeiša - Retreating Soldier 2
- Vladimir Chernyshov - Bezukhov Major-Domo
- Vincent Brimble - Bald Hills Doctor
- Mary Roscoe - Maria Bogdanovna
- Matthew Raymond - Nevitsky
- Dan Tetsell - Postmaster
- David Sibley - Bakshin
- Tim Bentinck - Shadowy Freemason
- Rory Keenan - Bilibin
- Milo Twomey - Grigori
- Nicholas McGaughey - Self Important Major
- Vidmantas Fijalkauskas - Pyotr
- Matthew Stagg - Nikolushka
- Emily Taaffe - Katya
- Otto Farrant - Petya Rostov
- Kate Fleetwood - Anisya
- Jay Villiers - Count Rastopchin
- Valerijus Jevsejevas - Bolkonsky Footman
- Janina Matekonytė - Dressmaker
- Edith Vernes - Mademoiselle George
- Harry Lister Smith - Lieutenant Ilyin
- Will Attenborough - Artillery Officer
- Adrian Rawlins - Platon Karataev
- Dovilė Kundrotaitė - Natasha's Maid
- Manuel Severi - Un garde français
- Alexander Bhat - Helene’s Lover
- Dainius Jankauskas - Andrei's Orderly
- Laura Lankester
- ??? ???????
- Andrew Davies
- Bethan Jones
- Susie Figgis
- Lina Miseikyte
- Martin Heriot
- Julia Stannard
- Harvey Weinstein
- Martin Phipps
Ludger Pistor hace el papel de General Mack.
Adrian Rawlins interpreta a Platon Karataev en la serie.
Lily James interpreta a Natasha Rostova en la serie.
James Norton hace el papel de Andrei Bolkonsky.
Paul Dano hace el papel de Pierre Bezukhov.
Gillian Anderson interpreta a Anna Pavlovna Scherer en la serie.
Jessie Buckley interpreta a Marya Bolkonskaya en la serie.
Aneurin Barnard interpreta a Boris Drubetskoy en la serie.
Greta Scacchi interpreta a Natalya Rostova en la serie.
Aisling Loftus hace el papel de Sonya Rostova.
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